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Plasticizers

Chemical Economics Handbook

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Published May 2021

Flexible polyvinyl chloride (PVC) accounts for 80–90% of global plasticizer consumption. Flexible PVC (and thus plasticizers) is found in the following applications: construction (flooring, wall coverings), electrical (wire and cable jacketing), consumer goods (toys, footwear, etc.), packaging, transportation (inside and outside of vehicles), furnishings, and medical uses (tubing, blood bags). Continued global demand for flexible PVC will lead to continued growth for plasticizers. Demand for most downstream plasticizer markets is greatly influenced by general economic conditions. As a result, demand for plasticizers largely follows the patterns of the leading world economies. Mainland China is the singlelargest plasticizer market in the world, accounting for over half of world consumption in 2020; it also has the highest forecast consumption growth during the next few years, spurred by increased plasticizer consumption in goods for both domestic and export markets. Overall, global plasticizer consumption will grow at a rate of about 3.5% per year in the next few years.

Phthalate esters, based on phthalic acid, are the main types of plasticizers used since they satisfy a broad range of processing and performance requirements, as well as a large number of markets. Major phthalates include di(2- ethylhexyl)phthalate (DEHP), also known as dioctyl phthalate (DOP); diisononyl phthalate (DINP); diisodecyl phthalate (DIDP); and di(2-propylheptyl) phthalate (DPHP). Nonphthalate plasticizers are not based on phthalic acid, and have a different chemical structure and toxicological profile. These include terephthalates (the most common is dioctyl terephthalate [DOTP]), epoxy, aliphatics, trimellitates, polymerics, phosphates, and others.

The following pie chart shows world consumption of plasticizers:

Phthalates accounted for over 55% of world consumption of plasticizers in 2020, down from approximately 60–65% a few years ago; they are forecast to account for 50–55% of world consumption in the coming years. The decrease in market share has largely been due to the following:

  • Rapid consumption growth for nonphthalate plasticizers, mainly terephthalates, epoxy, aliphatics, and benzoates, as replacements for DEHP and other phthalates, which are regulated in some regions because of potential human health risks
  • Continued growth of nonphthalates in different applications and markets
  • Ongoing pressure from retailers and consumers to limit the use of phthalates, especially in developed regions

Overall, phthalates will continue to exhibit modest growth. For example, DINP will experience growth throughout the world. World consumption of phthalate plasticizers is forecast to grow moderatley during 2021–25.

Nonphthalate plasticizers are not based on phthalic acid, and have a different chemical structure and toxicological profile. These include terephthalates (the most common is dioctyl terephthalate [DOTP]), epoxy, aliphatics, trimellitates, polymerics, phosphates, and others. There has been a continuing shift toward the use of nonphthalates, mainly because of increasing regulations on certain phthalates resulting from human health concerns. Nonphthalates are able to address some of the health concerns facing phthalates while meeting performance requirements.

There have also been phthalates replaced with other types of phthalates to address these issues. For example, global DEHP regulations have led to a phaseout or more limited use of DEHP in some regions, having been replaced with other phthalates, as well as nonphthalates.

World consumption of other plasticizers (terephthalates, epoxy, aliphatics, trimellitates, polymerics, benzoates, and phosphates) is forecast to grow strongly during 2021–25. For example, terephthalates, trimellitates, and some aliphatics are forecast to grow relatively strongly as they replace phthalates. In some regions, however, growth rates for these plasticizers will be slightly less than in previous years due to the replacement of phthalates having already occurred.

Although overall economic performance will continue to be the best indicator of future demand for plasticizers, other issues that may affect the market during the next five years include the following:

  • Availability and access to low-cost feedstocks
  • Raw material and energy costs
  • Environmental and health regulations affecting and/or limiting the type of plasticizers used, mainly phthalates

Phthalates continue to account for most global consumption at approximately 55%. There will be continued interest in the use and development of nonphthalate plasticizers.

For more detailed information, see the table of contents, shown below.

S&P Global’s Chemical Economics Handbook – Plasticizers is the comprehensive and trusted guide for anyone seeking information on this industry. This latest report details global and regional information, including

Key Benefits

S&P Global’s Chemical Economics Handbook – Plasticizers has been compiled using primary interviews with key suppliers and organizations, and leading representatives from the industry in combination with S&P Global’s unparalleled access to upstream and downstream market intelligence and expert insights into industry dynamics, trade, and economics.

This report can help you

  • Identify trends and driving forces influencing chemical markets
  • Forecast and plan for future demand
  • Understand the impact of competing materials
  • Identify and evaluate potential customers and competitors
  • Evaluate producers
  • Track changing prices and trade movements
  • Analyze the impact of feedstocks, regulations, and other factors on chemical profitability
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Table of Contents

Executive summary 9
Summary 10
Introduction 17
Plasticizers and plasticization 17
Phthalates 19
Terephthalates 19
Aliphatics 20
Epoxidized vegetable oils 20
Trimellitates 20
Benzoates 20
Phosphate plasticizers 20
Polymeric plasticizers 21
Manufacturing processes 22
Polycarboxylic acid esters 22
Terephthalates 22
Epoxidized vegetable oils 22
Phosphate plasticizers 22
Polymeric plasticizers 22
Environmental issues 24
United States 24
Western Europe 26
Asia 28
Mainland China 28
South Korea 28
Taiwan 29
Other 29
Supply and demand by region 31
United States 31
Producing companies 31
Arkema 33
BASF 33
CHS 33
Eastman 33
Emerald Kalama 33
ExxonMobil Chemical 33
Galata Chemicals 33
HallStar 34
ICL-IP 34
Inbra 34
LANXESS 34
Teknor Apex 34
Valtris 34
Vertellus 34
Westlake Chemical 34
Production 34
Phthalates 35
Aliphatics 37
Terephthalates 38
Epoxy plasticizers 38
Benzoates 39
Phosphate plasticizers 40
Trimellitates 41
Polymeric plasticizers 42
Other 42
Consumption 44
Phthalates 46
Diisononyl phthalate (DINP) 47
Diisodecyl phthalate (DIDP) 48
Di(2-propylheptyl) phthalate (DPHP) 482,48
Di(2-ethylhexyl) phthalate (DEHP, DOP, dioctyl phthalate) 482,48
n-Butyl benzyl phthalate (BBP) 49
Linear phthalates 49
Diundecyl phthalate (DUP) 50
Ditridecyl (DTDP) phthalate 50
Dimethyl phthalate (DMP) 50
Di-n-butyl phthalate (DBP) 51
Diethyl phthalate (DEP) 51
Other 51
Aliphatics 51
Adipates 52
Triethylene glycol di-2-ethylhexanoate 532,53
Alkane sulfonic esters of phenol (ASEPs) 53
Azelates and sebacates 53
Citrates 54
Other 54
Terephthalates 55
Dioctyl terephthalate (DOTP) 55
Di-n-butyl terephthalate (DBT) 56
Epoxy plasticizers 56
Benzoates 57
Dibenzoates 57
Other 58
Trimellitates 58
Trioctyl trimellitate (TOTM) 59
Triisononyl trimellitate (TINTM) 60
Other 60
Phosphate plasticizers 60
Aryl phosphates 60
Alkyl phosphates 61
Polymeric plasticizers 63
Other 63
TXIB® Formulation Additive 64
Sulfonamides 64
Miscellaneous 65
Price 65
Trade 65
Canada 67
Producing companies 67
BASF Canada 68
GEON Performance Solutions 68
Production 69
Consumption 69
Trade 70
Imports 70
Exports 71
Mexico 72
Producing companies 72
Especialidades Industriales y Químicas 72
Alphagary 73
Resinas y Materiales (Resymat) 73
Sintesis Organicas 73
Salient statistics 73
Consumption 73
Trade 74
Imports 74
Exports 75
Brazil 75
Producing companies 75
BBC 76
COIM Brasil 76
DPV Produtos 76
Elekeiroz 76
Inbra 76
Petrom 76
Taminco do Brasil Produtos Químicos 77
Production 77
Salient statistics 77
Consumption 78
Trade 78
Imports 78
Exports 79
Other Central and South America 79
Producing companies 79
Carboquímica 80
Irixcor 80
Lestar Química 80
Panimex Química 80
Petroquimica Sima 80
Varteco Química 80
Salient statistics 81
Consumption 81
Western Europe 83
Producing companies 83
Production 89
Consumption 90
Plasticizers from renewable/recycled sources 94
Phthalates 95
Epoxy plasticizers 97
Aliphatics 98
Alkane sulfonic esters of phenol 99
Adipates 99
Triethylene glycol di-2-ethylhexanoate 992,99
Sebacates 99
Other 99
Di-isononyl cyclohexanoates 100
Terephthalates 100
Benzoates 102
Dibenzoates 103
Monobenzoates 103
Polymeric plasticizers 104
Trimellitates 104
Phosphate plasticizers 104
Citrate plasticizers 105
Other 106
Sulfonamides 106
Pentaerythritol tetravalerate 106
Price 106
Trade 107
Imports 107
Exports 108
Central and Eastern Europe 109
Producing companies 109
Salient statistics 110
Consumption 111
CIS 112
Producing companies 112
Salient statistics 113
Consumption 113
Middle East 114
Producing companies 114
Salient statistics 116
Consumption 117
Africa 118
Producing companies 118
Salient statistics 118
Consumption 120
Indian Subcontinent 121
Producing companies 121
Salient statistics 122
Consumption 123
Trade 126
Mainland China 126
Producing companies 126
Salient statistics 136
Consumption 139
Phthalates and terephthalates 140
DEHP 140
DOTP 141
DINP 141
DBP/DIBP 142
DPHP 142
Epoxy plasticizers 143
Aliphatics 143
Trimellitates 143
Citrates 144
Other 144
Price 145
Trade 146
Imports 146
Exports 146
Japan 147
Producing companies 147
Production 149
Phthalates 150
Phosphate plasticizers 150
Adipates 150
Epoxy plasticizers 150
Trimellitates 150
Polymeric plasticizers 150
Other aliphatics 150
Other 151
Consumption 151
Phthalates and terephthalates 152
Adipates 154
Trimellitates 154
Epoxy plasticizers 154
Polymeric plasticizers 155
Phosphate plasticizers 155
Other 155
Price 156
Trade 156
Imports 156
Exports 157
Other Northeast Asia 158
Producing companies 158
Salient statistics 159
Consumption 160
Trade 162
Southeast Asia 164
Producing companies 164
Salient statistics 165
Consumption 166
Trade 169
Imports 169
Exports 169
Oceania 170
Salient statistics 170
Consumption 170
Additional resources 172
Revisions 173
Data Workbook 174

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