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Organometallics

Chemical Economics Handbook

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Published August 2020

The main product categories covered in this report are organotins, organoaluminums, organomagnesiums, and organolithiums.

Nonbiocidal organotins are used largely as additives for polyvinyl chloride (PVC), but also in catalysis of several products, including rigid polyurethanes and silicones. Biocidal organotins are used in agriculture as fungicides and miticides, and as preservatives/antifoulants on wood surfaces, in closed-circuit cooling towers, and in marine paints.

Organoaluminums are used primarily as catalysts for the synthesis of polymers, including polypropylene, polyethylene, and several elastomers. Use as a catalyst for other syntheses includes olefin oligomerization and the Dimersol process for gasoline production.

Organomagnesiums are used as catalysts for polyolefin production and in the synthesis of pharmaceutical and fine chemicals. Organolithiums are used as catalysts for polybutadiene elastomer production and in the synthesis of pharmaceuticals.

The following pie chart shows merchant consumption of organometallics by major region, based on value:

The overall business environment for organometallics includes the following characteristics:

  • Greater regulations and restrictions (e.g., tributyltins in markets such as biocides/paint and PVC stabilizers). Because of stricter environmental demands, organotin antifoulants have been phased out and replaced by copper-based or other alternatives.
  • Volatile raw materials (metals) costs, along with processing cost fluctuations, adversely affect the development of markets for some organometallics in certain applications (e.g., organotin stabilizers).
  • The rapid expansion and maturation of the LED and solar cell markets has hastened demand for high-purity organometallics for use in metal organic chemical vapor deposition and other thin-film applications.
  • Polyvinyl chloride additive applications remain the main markets for organotins, especially in mainland China and the United States.
  • Catalyst applications remain the main markets for organoaluminums, organomagnesiums, and organolithiums.

Organotins are the largest-volume products followed by the organoaluminums. Combined, the two account for more than 97% of the total volume and more than 90% of the total value of the global organometallics market. Mainland China is the largest consumer of organotins for PVC applications, while both China and the United States are nearly equal biocidal consumers. In organoaluminums, the United States remains the largest consumer, followed by mainland China, Western Europe, and the Middle East.


The US market for organotins, which is tied to the construction, housing, and home remodeling markets, has slowed recently, following years of recovery since the economic crisis in 2009. In 2020, the recession, compounded by temporary construction holds imposed due to COVID-19, led to declines for PVC and organotins.

The largest share of the organometallic market in Western Europe is accounted for by organotins (47%) and organoaluminums (44%). The commercial consumption of these organometallics in other regions (Central and Eastern Europe, the Middle East, and Africa) is relatively small. Western Europe had been the only producing area in the region, until 2013, when organoaluminum production began in the Middle East, to supply the region’s growing polyolefin production.
The development of mainland China’s organometallics market has been intrinsically tied to the country’s strong economic growth and the rapid expansion of the plastics industry. An insatiable buildup of capacity for PVC, polyethylene, and other resins hastened an equal need for sufficient supplies of organometallics. In 2019, mainland China accounted for nearly half of estimated global consumption of organotins and more than 20% of global consumption of organoaluminums, driven by growing production of PVC and polyolefins.

Japanese consumption of diorganotins for the PVC stabilizer market has remained at about the same level for the last five years; consumption of triorganotins ceased in 1999 as a result of environmental legislation. Organoaluminum consumption has been decreasing because of improved performance of organoaluminum catalysts and a general decline in polyolefin production. Overall, Japanese consumption of organometallics will be flat to declining over the next five years.
For more detailed information, see the table of contents, shown below.

S&P Global’s Chemical Economics Handbook –Organometallics is the comprehensive and trusted guide for anyone seeking information on this industry. This latest report details global and regional information, including

Key benefits

S&P Global’s Chemical Economics Handbook –Organometallics has been compiled using primary interviews with key suppliers and organizations, and leading representatives from the industry in combination with S&P Global’s unparalleled access to upstream and downstream market intelligence and expert insights into industry dynamics, trade, and economics.

This report can help you

  • Identify trends and driving forces influencing chemical markets
  • Forecast and plan for future demand
  • Understand the impact of competing materials
  • Identify and evaluate potential customers and competitors
  • Evaluate producers
  • Track changing prices and trade movements
  • Analyze the impact of feedstocks, regulations, and other factors on chemical profitability
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Table of Contents

Section Page Number

Executive summary 8
Summary 9
United States 12
Europe, the Middle East, and Africa 13
Mainland China 14
Japan 15
Introduction 16
Organotins 18
Description and properties 18
Nonbiocidal organotins—RSNX3 and R2SNX2 18 18
Description 18
Mechanism of PVC stabilization with mono- and dialkyltins 18
Biocidal organotins—R3SNX 193,19
Manufacturing processes 20
Nonbiocidal organotins 20
Biocidal organotins 21
Environmental issues 21
Supply and demand by region 23
United States 23
Producing companies 23
Consumption 25
Nonbiocidal organotins 25
Biocidal organotins 30
Price 33
Trade 35
Canada 36
Western Europe 37
Introduction 37
Corporate activities 37
Associations and interest groups 39
Rules and regulations 39
Producing companies 42
Salient statistics 43
Consumption 44
PVC 46
Catalysts 47
Glass coatings 48
Biocides 48
Price 48
Trade 49
Central and Eastern Europe 49
Salient statistics 49
Consumption 50
Middle East 51
Producing companies 51
Salient statistics 51
Consumption 52
Africa 53
Salient statistics 53
Consumption 54
Indian Subcontinent 54
Producing companies 54
Consumption 56
Mainland China 56
Producing companies 56
Salient statistics 57
Consumption 58
PVC stabilizers 59
Catalyst use 59
Biocidal use 59
Price 59
Trade 59
Japan 60
Producing companies 60
Production 61
Consumption 62
Price 64
Trade 64
Northeast Asia 65
Producing companies 65
Consumption 65
Southeast Asia and Oceania 65
Producing companies 65
Consumption 66
Organoaluminums 67
Description and properties 67
Manufacturing processes 68
Aluminum alkyls and hydrides 68
Aluminum halides and sesquihalides 69
Environmental issues 69
Supply and demand by region 70
United States 70
Producing companies 70
Consumption 71
Catalysts for polymer synthesis 72
Catalysts for other syntheses 83
Price 84
Trade 85
Canada 85
Western Europe 86
Producing companies 86
Salient statistics 88
Consumption 89
Price 90
Trade 91
Central and Eastern Europe 91
Middle East 92
Africa 92
Indian Subcontinent 93
Producing companies 93
Consumption 94
Mainland China 94
Producing companies 94
Consumption 94
Price 95
Japan 95
Producing companies 95
Salient statistics 96
Consumption 97
Price 100
Trade 100
Imports 100
Exports 100
Northeast Asia 100
Producing companies 100
Consumption 101
Southeast Asia and Oceania 101
Consumption 101
Organomagnesiums and organolithiums 103
Description and properties 103
Organomagnesium compounds 103
Organolithium compounds 103
Manufacturing processes 104
Organomagnesium compounds 104
Organolithium compounds 104
Environmental issues 105
Supply and demand by region 105
United States 105
Producing companies 105
Consumption 107
Organomagnesium compounds 108
Organolithium compounds 109
Price 110
Trade 111
Western Europe 111
Producing companies 111
Organomagnesium compounds 111
Organolithium compounds 112
Salient statistics 112
Organomagnesium compounds 112
Organolithium compounds 113
Price 115
Trade 115
Central and Eastern Europe 116
Middle East 116
Africa 116
Indian Subcontinent 116
Mainland China 117
Producing companies 117
Consumption 118
Organomagnesiums 118
Organolithiums 118
Price 118
Japan 119
Producing companies 119
Organomagnesium compounds 119
Organolithium compounds 119
Consumption 120
Organomagnesium compounds 120
Organolithium compounds 120
Price 120
Trade 120
Northeast Asia 120
Organozincs 121
Description and properties 121
Supply and demand by region 121
United States 121
Producing companies 121
Consumption 122
Trade 122
Western Europe 123
Producing companies 123
Salient statistics 123
Consumption 124
Price 125
Trade 125
Central and Eastern Europe 125
Middle East 125
Africa 125
Indian Subcontinent 126
Mainland China 126
Producing companies 126
Consumption 126
Price 126
Japan 126
Northeast Asia 127
Additional resources 128
Revisions 130

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