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Miscellaneous Sulfur Chemicals

Chemical Economics Handbook

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Published December 2020

This report reviews the merchant markets for sulfur dioxide and other miscellaneous sulfur chemicals: sulfur dioxide, sodium hydrosulfide, sodium hydrosulfite, sodium sulfide, sodium sulfites, sodium thiosulfate, and sodium formaldehyde sulfoxylate. Although demand into sulfuric acid is noted for some regions, full discussion of that market can be found in the CEH Sulfuric Acid report.

Consumption of these compounds varies widely by region, depending on the regional requirements for the major end-use markets—reducing and bleaching agents in the pulp and paper and textile industries, as well as in the photographic and food industries, and as precipitating and reducing agents in the treatment of water.

The following pie charts show world consumption of miscellaneous sulfur chemicals by type and by region:

Where competing products exist, liquid sulfur dioxide is almost always the lowest-cost alternative. However, concerns over safety in transport, handling, storage, and use are often the impetus for substitution. Competing products in some applications include sodium sulfites (SS, SBS, and MBS) and sodium thiosulfate, which can either be coproducts in the manufacture of liquid sulfur dioxide or produced directly/captively from a liquid sulfur dioxide feed.

The markets that are anticipated to experience the largest growth over the forecast period include mineral ore processing, oil recovery, and use as a chemical intermediate for other sulfur compounds, including the manufacture of ammonium bisulfite, ammonium thiosulfate, and polyphenylene sulfide (PPS) resins.

Although developing regions may experience higher-than-average demand in some applications, the majority of end-use markets are mature and reflect very little and even declining growth. Furthermore, the growth potential for sulfur dioxide remains challenged by mounting regulations and environmental pressures, as well as the high risks and costs associated with handling and transportation.

Mainland China has taken a leading position for most derivative markets and has become the major global supplier. The rapid development in mainland China’s metal manufacturing (smelting operations) as well as increased demand for sulfuric acid in domestic fertilizer production has propelled the mainland Chinese sulfur industry. This expansion occurred at the same time as implementation of a series of environmental regulations to reduce sulfur dioxide emissions, which resulted in an overall contraction in most industrialized regions. Derivative manufacture will remain a primary outlet for mainland Chinese sulfur dioxide, particularly as efforts to further reduce emissions take hold.

For more detailed information, see the table of contents, shown below.

S&P Global’s Chemical Economics Handbook – Sulfur Chemicals, Miscellaneous is the comprehensive and trusted guide for anyone seeking information on this industry. This latest report details global and regional information, including

Key Benefits

S&P Global’s Chemical Economics Handbook – Sulfur Chemicals, Miscellaneous has been compiled using primary interviews with key suppliers and organizations, and leading representatives from the industry in combination with S&P Global’s unparalleled access to upstream and downstream market intelligence and expert insights into industry dynamics, trade, and economics.

This report can help you

  • Identify trends and driving forces influencing chemical markets
  • Forecast and plan for future demand
  • Understand the impact of competing materials
  • Identify and evaluate potential customers and competitors
  • Evaluate producers
  • Track changing prices and trade movements
  • Analyze the impact of feedstocks, regulations, and other factors on chemical profitability
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Table of Contents

Executive summary 13
Summary 14
Sulfur dioxide 15
Sodium hydrosulfide 16
Sodium hydrosulfite 16
Sodium sulfide 17
Sodium sulfites 18
Sodium thiosulfate 21
Sodium formaldehyde sulfoxylate 22
Introduction 24
Markets 25
Pulp and paper 25
Leather industry 25
Food processing 25
Water treatment 25
Textile dyeing 25
Photography 26
Kaolin bleaching 26
Manufacturing processes 27
Sulfur dioxide 27
Sodium hydrosulfide 28
Sodium hydrosulfite 28
Sodium formate process 28
Mercury amalgam and electrolytic 28
Zinc sodiation process 29
Borohydride-generated hydrosulfite (BGH) 29
Sodium sulfide 30
Sodium sulfite 31
Sodium thiosulfate 32
Sodium formaldehyde sulfoxylate 33
Supply and demand by region 34
United States 34
Sulfur dioxide 34
Producing companies 34
Salient statistics 35
Consumption 35
Price 37
Trade 38
Imports 38
Exports 39
Sodium hydrosulfide 39
Producing companies 39
Salient statistics 41
Consumption 42
Mineral processing 42
Pulp and paper 42
Chemicals and dyes 43
Leather processing 43
Other 43
Price 43
Trade 44
Imports 45
Exports 45
Sodium hydrosulfite 46
Producing companies 46
Salient statistics 47
Consumption 47
Paper pulp bleaching 48
Clay leaching 48
Textile dyeing 49
Price 50
Trade 51
Imports 51
Exports 51
Sodium sulfide 52
Producing companies 52
Salient statistics 53
Consumption 53
Mineral processing 54
Pulp and paper 54
Chemicals and dyes 54
Leather processing 54
Other 55
Price 55
Trade 55
Sodium sulfites 56
Overview 56
Producing companies 56
Salient statistics 58
Sodium sulfite 59
Producing companies 59
Salient statistics 59
Consumption 60
Price 61
Trade 61
Sodium metabisulfite 62
Producing companies 62
Salient statistics 62
Consumption 63
Trade 63
Sodium bisulfite (SBS) 64
Producing companies 64
Salient statistics 64
Consumption 65
Sodium thiosulfate 65
Producing companies 65
Salient statistics 65
Consumption 66
Dry 67
Solution 67
Price 67
Trade 68
Sodium formaldehyde sulfoxylate 69
Salient statistics 69
Consumption 70
Trade 70
Canada 71
Sulfur dioxide 71
Producing companies 71
Salient statistics 71
Consumption 72
Trade 73
Sodium hydrosulfide 74
Salient statistics 74
Consumption 75
Trade 75
Sodium hydrosulfite 76
Producing companies 76
Salient statistics 77
Consumption 78
Price 79
Trade 79
Sodium sulfide 80
Salient statistics 81
Consumption 81
Trade 81
Sodium sulfites 81
Sodium sulfite (SS) 82
Sodium metabisulfite (MBS) 83
Sodium bisulfite solution (SBS) 83
Producing companies 83
Salient statistics 84
Consumption 84
Sodium thiosulfate 85
Sodium formaldehyde sulfoxylate (SFS) 85
Mexico 85
Sulfur dioxide 86
Salient statistics 86
Consumption 86
Trade 86
Sodium hydrosulfide 87
Producing companies 87
Salient statistics 87
Consumption 88
Trade 88
Sodium hydrosulfite 89
Consumption 89
Price 89
Imports 90
Sodium sulfide 91
Producing companies 91
Salient statistics 91
Consumption 91
Trade 91
Sodium sulfites 92
Producing companies 92
Salient statistics 92
Consumption 93
Trade 93
Sodium thiosulfate 94
Producing companies 94
Salient statistics 94
Consumption 94
Trade 94
Sodium formaldehyde sulfoxylate 95
Central and South America 95
Sulfur dioxide 96
Producing companies 96
Salient statistics 96
Consumption 97
Trade 97
Sodium hydrosulfide 98
Producing companies 98
Salient statistics 98
Consumption 99
Mineral processing 99
Leather processing 99
Other 100
Trade 100
Imports 100
Exports 101
Sodium hydrosulfite 102
Salient statistics 102
Consumption 103
Trade 103
Sodium sulfide 104
Producing companies 104
Salient statistics 105
Consumption 106
Trade 106
Imports 106
Exports 107
Sodium sulfites 108
Producing companies 108
Salient statistics 108
Consumption 111
Trade 111
Imports 111
Exports 112
Sodium thiosulfate 113
Producing companies 113
Salient statistics 113
Consumption 113
Trade 114
Sodium formaldehyde sulfoxylate 115
Salient statistics 115
Consumption 116
Trade 116
Western Europe 117
Sulfur dioxide 118
Producing companies 118
Salient statistics 120
Production 120
Consumption 120
Price 122
Trade 122
Sodium hydrosulfide 123
Producing companies 123
Salient statistics 124
Consumption 125
Chemical processing and textile dyeing 126
Pulp processing 126
Water treatment/mining 126
Leather processing 126
Trade 127
Sodium hydrosulfite 127
Producing companies 127
Salient statistics 128
Consumption 129
Pulp and paper industry 130
Textile industry 130
Kaolin and other 131
Price 131
Trade 131
Sodium sulfide 132
Producing companies 132
Salient statistics 132
Consumption 133
Price 134
Trade 134
Sodium sulfites 134
Producing companies 134
Salient statistics 135
Production 139
Consumption 139
Sodium sulfite 139
Sodium metabisulfite 140
Sodium bisulfite 140
Price 140
Trade 140
Sodium thiosulfate 141
Producing companies 141
Salient statistics 141
Consumption 142
Price 143
Trade 143
Sodium formaldehyde sulfoxylate 144
Producing companies 144
Salient statistics 144
Consumption 145
Price 145
Trade 145
Central and Eastern Europe 145
Sulfur dioxide 146
Sodium hydrosulfide 147
Sodium hydrosulfite 150
Sodium sulfides 151
Sodium sulfites 154
Salient statistics 155
Consumption 157
Trade 158
Sodium thiosulfate 160
Salient statistics 160
Consumption 161
Trade 162
Sodium formaldehyde sulfoxylate 163
Middle East and Africa 163
Sulfur dioxide 165
Producing companies 165
Salient statistics 165
Consumption 166
Trade 166
Sodium hydrosulfide 166
Producing companies 166
Salient statistics 167
Consumption 168
Trade 169
Sodium hydrosulfite 170
Producing companies 170
Salient statistics 170
Consumption 171
Trade 171
Sodium sulfide 172
Producing companies 172
Salient statistics 172
Consumption 173
Trade 173
Sodium sulfites 176
Producing companies 176
Salient statistics 177
Consumption 179
Trade 180
Sodium thiosulfate 181
Salient statistics 181
Consumption 182
Trade 182
Sodium formaldehyde sulfoxylate 183
Salient statistics 183
Consumption 184
Trade 184
Asia 185
Mainland China 185
Sulfur dioxide 185
Producing companies 185
Salient statistics 186
Consumption 187
Price 188
Trade 188
Sodium hydrosulfide 188
Producing companies 188
Salient statistics 189
Consumption 190
Price 191
Trade 191
Sodium hydrosulfite 193
Producing companies 193
Salient statistics 194
Consumption 195
Price 195
Trade 196
Sodium sulfide 197
Producing companies 197
Salient statistics 198
Consumption 199
Price 200
Trade 200
Sodium sulfites 201
Producing companies 201
Salient statistics 203
Consumption 205
Price 207
Trade 207
Sodium thiosulfate 209
Producing companies 209
Salient statistics 209
Consumption 210
Price 211
Trade 211
Sodium formaldehyde sulfoxylate 212
Producing companies 212
Salient statistics 213
Consumption 213
Price 214
Trade 214
Other Asia 215
Sulfur dioxide 215
Producing companies 215
Salient statistics 216
Consumption 217
Price 217
Trade 217
Sodium hydrosulfide 217
Producing companies 217
Salient statistics 218
Consumption 219
Price 220
Trade 220
Sodium hydrosulfite 220
Producing companies 220
Salient statistics 221
Consumption 221
Price 222
Trade 222
Sodium sulfide 223
Producing companies 223
Salient statistics 224
Consumption 225
Price 225
Trade 225
Sodium sulfites 225
Producing companies 225
Salient statistics 226
Consumption 229
Price 230
Trade 230
Sodium thiosulfate 231
Producing companies 231
Salient statistics 232
Consumption 233
Price 234
Trade 234
Sodium formaldehyde sulfoxylate 234
Producing companies 234
Salient statistics 235
Consumption 236
Trade 236
Imports 236
Exports 236
Additional resources 238
Revisions 239
Data Workbook 240

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