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Hydrogen Peroxide

Chemical Economics Handbook

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Published August 2021

In most markets, hydrogen peroxide functions as a bleach or oxidizer. As such, it often competes with other chemicals capable of performing similarly. Some derivatives (e.g., perborates) also function as bleaching or oxidizing agents. Regional cost differences, consumer preferences and technical differences in product performance enter into the decision to use hydrogen peroxide or one of its derivatives rather than another product. Since these considerations vary by region, the consumption patterns vary in different parts of the world.

The hydrogen peroxide market is dominated by the pulp and paper industry, with the main uses being in pulp bleaching and deinking of recycled paper. Growth of the pulp industry has been particularly strong in Southeast Asia and Central and South America. Both regions have the competitive advantage of fast-growing eucalyptus as pulp raw material, and accordingly, investment in new pulp mills is made primarily in these regions. Southeast Asian producers have an additional advantage—their proximity to growing markets.

The following pie chart shows world consumption of hydrogen peroxide:

hydrogen-peroxide

During 2018–23, the hydrogen peroxide market is expected to continue to grow. The change from print to digital media has been ongoing for many years, and it had been expected that this trend would result in decreasing paper consumption, as well as decreasing hydrogen peroxide consumption. Yet, increasing paper consumption in the developing parts of the world and increasing demand for hygiene paper, tissues, and packaging have outbalanced the shrinking use in newsprint in the developed world. In the current forecast period, the continued switch to digital media and shrinking paper consumption is expected to result in stagnation of this hydrogen peroxide market segment. However, the packaging as well as hygiene paper sectors are both expected to grow at healthy rates, and to outpace the adverse effect.

The downstream chemical markets are expected to grow, with the exception of sodium percarbonate. The trend toward liquid detergents continues at the expense of powder detergent use, and percarbonate use accordingly. Perborate is having a renaissance, after nearly disappearing in powder detergents. Consumption volumes are increasing at a fast rate in the North American unconventional oil market. Uses of hydrogen peroxide and peracetic acid as a disinfectant, for microbial control, for animal hygiene, and in environmental and industrial areas of use are also growing at healthy rates. The single most important use of hydrogen peroxide in this segment is the production of propylene oxide via the HPPO process.

The first HPPO plant was started up in 2008 by SKC/Evonik in South Korea. In the meantime, other plants using the same technology were started up in Europe, the Middle East, and other Asian countries, and are running with high capacity utilization rates as they provide a competitive production route to propylene oxide. Additional HPPO plants are under construction or plans to build them in Asia and the Commonwealth of Independent States (CIS) have been announced. No plant has been announced yet for North America; however, cheap energy costs would allow highly competitive production of hydrogen peroxide, which coupled with availability of propylene feedstock, make it likely that an HPPO plant could also be built in the coming years.

Other smaller segments of downstream chemical use, i.e., epoxidized vegetable oils and peracetic acid, are also growing and they are being increasingly used as plasticizers in a growing plastics market and as an oxidizing agent, respectively.

Consumption of hydrogen peroxide as an oxidizing agent in the environmental segment has grown significantly in the last five years. Hydrogen peroxide has the reputation of being an environmentally friendly and efficient product. As environmental awareness is increasing globally and legislative requirements are becoming more stringent, this market is expected to remain important in the forecast period and result in increasing consumption of hydrogen peroxide.

Specialty grades of hydrogen peroxide are being used in food, cosmetics, and the electronics industry, and have been growing in line with growth in these industries. For the forecast period it is expected that a growing world population, increasing average wealth, and increasing disposable incomes will continue to result in growing consumption of hydrogen peroxide in these sectors.

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Table of Contents

Section Page Number

Executive summary 7
Summary 8
Introduction 13
Manufacturing processes 14
Anthraquinone autoxidation 14
Electrolysis 15
Direct synthesis 15
Other 16
Supply and demand by region 17
North America 17
United States 19
Producing companies 19
Salient statistics 20
Consumption 22
Pulp and paper mills 24
Chemicals and laundry products 24
Environmental applications 27
Textiles 29
Specialty grades 29
Price 31
Trade 32
Imports 32
Exports 33
Canada 34
Producing companies 34
Salient statistics 34
Consumption 35
Pulp and paper 36
Mining and environmental 36
Other 37
Trade 37
Imports 37
Exports 38
Mexico 39
Salient statistics 39
Consumption 39
Trade 40
Imports 40
Exports 41
Central and South America 41
Producing companies 41
Salient statistics 43
Consumption 44
Pulp and paper 45
Chemicals and laundry products 45
Mining 46
Other 46
Trade 46
Imports 46
Exports 47
Western Europe 47
Producing companies 47
Salient statistics 50
Production 50
Consumption 51
Pulp and paper 53
Chemicals and laundry products 54
Laundry products 56
Other inorganic and organic chemicals 57
Textiles 59
Environmental applications 59
Other 59
Price 60
Trade 61
Central and Eastern Europe 63
Producing companies 63
Salient statistics 64
Consumption 64
Trade 66
Commonwealth of Independent States (CIS) 67
Producing companies 67
Salient statistics 68
Consumption 69
Pulp and paper 69
Downstream chemical use 69
Sodium percarbonate 70
Propylene oxide 70
Mining 70
Trade 70
Middle East and Africa 72
Salient statistics 73
Consumption 74
Trade 75
India 77
Producing companies 77
Salient statistics 78
Consumption 79
Trade 80
Mainland China 81
Producing companies 81
Salient statistics 86
Consumption 86
Pulp bleaching 87
Textile bleaching 87
Chemical manufacture 88
Inorganic peroxides 88
Thiourea dioxide 89
Caprolactam 90
Propylene oxide 90
Epoxidized oils 91
Organic peroxides 91
Environment and water treatment 91
Other 92
Price 92
Trade 92
Japan 93
Producing companies 93
Salient statistics 94
Consumption 95
Chemicals and laundry products 96
Organic chemicals 96
Inorganic chemicals and laundry products 96
–Water treatment 97
Electronics 97
Pulp and paper 98
Textiles 98
Food 98
Other 98
Price 98
Trade 99
Imports 99
Exports 100
South Korea 101
Producing companies 101
Salient statistics 102
Consumption 103
Trade 103
Taiwan 104
Producing companies 104
Salient statistics 105
Consumption 106
Trade 106
Other Asia and Oceania 107
Producing companies 108
Salient statistics 110
Consumption 111
Bangladesh 113
Indonesia 113
Malaysia 113
Myanmar 113
Pakistan 113
Singapore 114
Thailand 114
Other 114
Oceania 114
Trade 114
Additional resources 117
Revisions 118
Data Workbook 119
Notice 120

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