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Chlorine-Sodium Hydroxide (Chlor-Alkali)

Chemical Economics Handbook

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Published December 2023

This report presents world capacity, production and consumption of chlorine and caustic soda (sodium hydroxide, NaOH) by region and application for 2012–22, with a forecast to 2027. It does not cover the production of potassium hydroxide (KOH), but includes the chlorine coproduced with KOH. Global chlor-alkali consumption is a function of global economic growth or decline. Chlorine demand is driven primarily by the construction sector, while caustic soda demand is driven primarily by the manufacturing sector. Chlorine consumption is largely dependent on the vinyl chain, which includes the production of EDC, VCM and PVC. Demand for chlor-alkali roughly follows worldwide GDP; however, aggregate global growth or decline does not account for the differences in regions, masking the stronger growth in developing countries versus mature (developed) economies.

The following charts show world consumption of chlorine and caustic soda:

Chlorine-Sodium Hydroxide

Chlorine-Sodium Hydroxide

Most chlor-alkali capacity is built to supply feedstock for the vinyl chain (EDC, VCM and PVC), demand for which is strongly correlated with construction spending and the general health of the construction industry. The vinyl chain currently represents over one-third of the global chlorine market. Thus, chlorine consumption and production are strongly driven by the construction industry, and depend on the growth of the global economy, since a country will spend more on construction if it has a healthy GDP.

Other organic chemical markets (propylene oxide, epichlorohydrin, TDI, MDI, polycarbonate and chlorinated intermediates) accounted for more than one-fourth of chlorine consumption in 2022, while use for inorganic chemicals, pulp and paper and water treatment together accounted for about 10% of the total.

Several trends have affected the chlor-alkali market. The first is the pace at which mainland China has reached a position of self-sufficiency in chlor-alkali and polyvinyl chloride (PVC) capacity. The second is the reduced cost of natural gas in the United States owing to the shale oil/gas boom, which has allowed it to regain its low-cost advantage for producing chlor-alkali and the vinyl chain, with only the Middle East having a lower cost basis. Future chlorine and VCM production will also be affected by the Minamata Convention on Mercury, which has called for catalyst replacement in mercury-based processes, such as mercury cell technology for chlorine production and the mercury-based catalyst used for converting acetylene to VCM. Mercury-based chlor-alkali plants are required to be phased out by 2025, with the possibility of two five-year extensions. In addition, no new VCM plants will not be allowed to use a mercury catalyst, and all VCM plants have to switch to a mercury-free catalyst within five years after a technically and economically viable alternative becomes available. As a result, mercury cell–based chlorine capacity has continued to decline, and there are not likely to be future expansions of acetylene-based VCM/PVC capacity.

For more detailed information, see the table of contents, shown below.

S&P Global’s Chemical Economics Handbook – Chlorine-Sodium Hydroxide (Chlor-Alkali) is the comprehensive and trusted guide for anyone seeking information on this industry. This latest report details global and regional information, including

Chlorine-Sodium Hydroxide

Key Benefits

S&P Global’s Chemical Economics Handbook – Chlorine-Sodium Hydroxide (Chlor-Alkali) has been compiled using primary interviews with key suppliers, organizations and leading representatives from the industry in combination with S&P Global’s unparalleled access to upstream and downstream market intelligence, expert insights into industry dynamics, trade and economics.

This report can help you:

  • Identify trends and driving forces influencing chemical markets
  • Forecast and plan for future demand
  • Understand the impact of competing materials
  • Identify and evaluate potential customers and competitors
  • Evaluate producers
  • Track changing prices and trade movements
  • Analyze the impact of feedstocks, regulations, and other factors on chemical profitability
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Contents

Executive summary7
Summary8
Salient statistics 11
Chlorine 11
Caustic soda (sodium hydroxide) 13
Capacity 15
Chlorine 15
Caustic soda (sodium hydroxide) 17
Production 17
Chlorine 17
Caustic soda (sodium hydroxide) 18
Consumption 18
Chlorine 18
Caustic soda (sodium hydroxide) 24
Trade 25
Introduction33
Manufacturing processes34
Coproduction of chlorine and caustic 34
Diaphragm cell 34
Mercury cell 35
Membrane cell 36
Without coproduction of either chlorine or caustic 36
Chlorine 37
Chlorine from hydrogen chloride 37
Chlorine as a by-product of metal production 37
Chlorine coproduction with potassium hydroxide 37
Other chlorine production processes 37
Caustic/sodium hydroxide 38
Major end uses39
Chlorine 39
Vinyls 39
Propylene oxide and phosgene 39
Epichlorohydrin 40
Intermediate chemicals 40
Chlorinated methanes 40
Chlorinated ethanes 41
Inorganic chemicals 42
Water treatment 44
Pulp and paper 45
Other 45
Sodium hydroxide (caustic) 46
Pulp and paper 47
Alumina 48
Propylene oxide 48
Polycarbonates 48
Epichlorohydrin 49
Organic chemicals 49
Inorganic chemicals 51
Soaps and detergents 53
Textiles 54
Water treatment 55
Other 55
Environmental issues57
Supply and demand by region59
North America 59
Overview 59
Capacity 59
Salient statistics 60
Production 61
Consumption 63
Trade 68
United States 69
Producing companies 70
Salient statistics 74
Consumption 76
Trade 78
Canada 80
Producing companies 80
Salient statistics 81
Consumption 83
Trade 86
Mexico 87
Producing companies 87
Salient statistics 89
Consumption 91
Trade 94
Central and South America 96
Producing companies 96
Salient statistics 100
Production 102
Consumption 102
Trade 105
Europe 107
Western Europe 107
Producing companies 108
Salient statistics 116
Consumption 117
Trade 120
Central and Eastern Europe 122
Producing companies 123
Salient statistics 127
Production 129
Consumption 129
Trade 132
CIS and Baltic States 133
Producing companies 134
Salient statistics 136
Production 138
Consumption 138
Trade 141
Middle East 142
Producing companies 143
Salient statistics 147
Production 149
Consumption 149
Trade 151
Africa 153
Producing companies 154
Salient statistics 158
Production 160
Consumption 160
Trade 163
Indian Subcontinent 164
Producing companies 165
Salient statistics 169
Production 170
Consumption 170
Trade 173
Northeast Asia 174
Overview 175
Capacity 175
Salient statistics 177
Production 179
Consumption 181
Trade 186
Mainland China 187
Producing companies 188
Salient statistics 202
Consumption 204
Trade 207
Japan 209
Producing companies 209
Salient statistics 212
Consumption 214
Trade 216
South Korea 218
Producing companies 218
Salient statistics 220
Consumption 222
Trade 224
Taiwan 226
Producing companies 226
Salient statistics 228
Consumption 229
Trade 231
Southeast Asia 233
Producing companies 234
Salient statistics 238
Production 240
Consumption 240
Trade 243
Additional resources245
Revisions246
Data Workbook247

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