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Bromine

Chemical Economics Handbook

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Published December 2021

Bromine is used in numerous inorganic and organic compounds. Since it is an element, it cannot be substituted by other materials without the properties of the compound being changed, often significantly. However, some bromine compounds, especially organic compounds, are susceptible to substitution by products with completely different chemistries. Important attributes for its use in inorganic compounds include its oxidation potential and its relatively high molecular weight (compared with chlorine).

In 2021, four bromine producers (Albemarle, Chemtura [now owned by LANXESS], Jordan Bromine, and ICL) accounted for more than 85% of the total global production capacity. Producers in mainland China, India, and the CIS countries are much smaller. Major producers are highly integrated, producing a wide variety of brominated end-use chemicals and intermediates, primarily from bromine or from hydrobromic acid produced as a by-product of bromination.

The following pie chart shows world consumption of bromine compounds:

bromine

The largest application for bromine-based compounds is in the production of brominated flame retardants (BFRs), accounting for 50% (100% bromine content) of total global consumption in 2021. Because the market is global, legislation in one region of the world has an impact on the type and use of flame retardants in another. Much of the environmental and toxicological concerns over the use of BFRs have been initiated in Europe. Hexabromocyclododecane (HBCD) is no longer allowed for use as a flame retardant in certain regions—Japan (2014), the European Union (2015), and Canada (year-end 2016). It is being replaced mainly by brominated polymeric flame retardants.

Clear brine fluids (CBFs) constitute the second-largest end-use market, accounting for 15% (100% bromine content) of 2021 global consumption of bromine-based compounds, most of which is used in North America. CBFs are used for the production of crude oil in deep, high-pressure wells where conventional drilling muds can plug the formations; there is also increased use for the development of nonconventional sources such as deepwater wells and oil sands. The Gulf of Mexico is one of the leading consuming regions.

Water treatment accounted for 8% (on a 100% bromine content basis) of the global consumption of brominebased compounds in 2021. The majority is consumed in mainland China and the United States, with a smaller amount consumed in Western Europe. Products used in this segment are brominated hydantoins and sodium/ammonium bromides. Consumption is broken down nearly equally between hydantoins and bromides.

Consumption of hydrogen bromide (HBr) used as a catalyst in the production of purified terephthalic acid (TPA) accounts for nearly 12% (100% bromine content) of the 2021 global consumption of bromine-based compounds. TPA is used in polyethylene terephthalate (PET) production; PET is ultimately used in packaging and fibers.

Consumption of methyl bromide (bromomethane) accounts for less than 3% (100% bromine content) of the 2021 world consumption of bromine-based compounds. Included in this is dibromomethane (methylene dibromide), which has different use than methyl bromide. Consumption of methyl bromide as a fumigant is declining, as this compound is considered a Class I ozone-depleting substance under the Montreal Protocol on Ozone Depleting Substances.

Overall, demand for elemental bromine is forecast to grow at 2–3% annually during 2021–26. The relatively high growth rate is driven by the recovery of the industry from the decline during the COVID-19 pandemic, as well as the expectation of higher oil prices.

For more detailed information, see the table of contents, shown below.

S&P Global’s Chemical Economics Handbook –Bromine is the comprehensive and trusted guide for anyone seeking information on this industry. This latest report details global and regional information, including

Key benefits

S&P Global’s Chemical Economics Handbook –Bromine has been compiled using primary interviews with key suppliers and organizations, and leading representatives from the industry in combination with S&P Global’s unparalleled access to upstream and downstream market intelligence and expert insights into industry dynamics, trade, and economics.

This report can help you

  • Identify trends and driving forces influencing chemical markets
  • Forecast and plan for future demand
  • Understand the impact of competing materials
  • Identify and evaluate potential customers and competitors
  • Evaluate producers
  • Track changing prices and trade movements
  • Analyze the impact of feedstocks, regulations, and other factors on chemical profitability
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Table of Contents

Section Page Number

Executive summary 7
Summary 8
Reserves and resources 8
Producing companies 8
Supply/demand 9
Production 10
Consumption 11
Brominated flame retardants 12
Clear brine fluids 12
Water treatment/biocides 13
Catalyst for purified terephthalic acid (TPA) 13
Methyl bromides 13
Other 14
Introduction 15
Abbreviations 15
Trade codes 16
Transportation 17
Manufacturing processes 19
Environmental issues 20
Supply and demand by region 23
United States 23
Reserves and resources 23
Producing companies 23
Salient statistics 25
Production 27
Consumption 28
Flame retardants 30
Additive BFRs 31
Reactive BFRs 32
Polymeric BFRs 33
Clear brine fluids 33
Water treatment 34
Environmental 35
Bromobutyl rubber 35
Catalyst for purified terephthalic acid (TPA) 36
Methyl bromide (brominated agricultural chemicals) 36
Other 37
Gasoline additives (ethylene dibromide) 37
Brominated intermediate uses 37
Price 38
Trade 41
Imports 42
Exports 44
Canada 45
Salient statistics 45
Consumption 47
Brominated flame retardants 47
Clear brine fluids 48
Water treatment 48
Terephthalic acid (TPA) 48
Methyl bromide 49
Other 49
Price 49
Trade 50
Mexico 50
Salient statistics 50
Consumption 51
Brominated flame retardants 52
Terephthalic acid (TPA) 52
Clear brine fluids 52
Methyl bromide 52
Price 52
Trade 53
Central and South America 54
Salient statistics 54
Consumption 55
Brominated flame retardants 55
Terephthalic acid (TPA) 56
Clear brine fluids 56
Methyl bromide 56
Pharmaceutical and agricultural/pesticide intermediates 56
Price 56
Trade 57
Western Europe 58
Producing companies 58
Salient statistics 59
Consumption 59
Price 61
Trade 62
Imports 62
Exports 63
Central and Eastern Europe 64
Producing companies 64
Salient statistics 65
Consumption 65
Price 66
Trade 67
Imports 67
Exports 67
Middle East 67
Producing companies 67
Salient statistics 68
Consumption 68
Price 69
Trade 70
Imports 70
Exports 70
Africa 71
Salient statistics 71
Consumption 72
Price 72
Trade 73
Imports 73
Exports 73
Mainland China 73
Producing companies 74
Salient statistics 76
Consumption 76
Brominated flame retardants 77
TPA 77
Clear brine fluids 78
Water treatment 78
Butyl rubber 78
Methyl bromide and dibromide 78
Other 79
Price 79
Trade 80
Imports 80
Exports 81
Japan 81
Producing companies 82
Salient statistics 82
Consumption 82
Price 83
Trade 84
Imports 84
Exports 85
South Korea 85
Salient statistics 85
Consumption 86
Price 86
Trade 87
Imports 87
Exports 87
Taiwan 88
Salient statistics 88
Consumption 88
Price 89
Trade 90
Imports 90
Exports 90
India 91
Producing companies 91
Salient statistics 91
Consumption 92
Price 93
Trade 93
Imports 93
Exports 94
Other Asia and Oceania 94
Salient statistics 94
Consumption 95
Price 96
Trade 96
Imports 96
Exports 97
Additional resources 98
Revisions 99
Data Workbook 100
Notice 101

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