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Linear and Branched Alkylbenzenes

Chemical Economics Handbook

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Published July 2021

Linear alkylbenzene (LAB) is produced by reacting benzene with alkyl groups containing 10 to 13 carbon atoms that are derived from normal (straight-chain) paraffins or linear alpha-olefins. Nearly all LAB is converted to linear alkylbenzene sulfonate (LAS) by sulfonation. LAS is the world’s largest-volume synthetic surfactant (including the various salts of sulfonated alkylbenzenes) and is the major surfactant used in household and industrial detergents. Branched alkylbenzene (BAB) is also sulfonated to produce a branched alkylbenzene sulfonate (BAS) that can be used in the same applications as LAS. However, BAS is slow to biodegrade in waste treatment plants; consequently, it has been replaced by LAS in household detergent applications in the developed countries, but continues to be used in some industrial applications in the developed countries. Its use in household detergent applications has been declining in the less-developed countries as well, because BAS is more expensive to produce than LAS. Branched alkylbenzene is also more expensive than LAB because of tight propylene tetramer supply and price.

The following pie chart shows world consumption of linear alkylbenzene in 2020:

Over the forecast period, consumption of linear alkylbenzene is expected to increase at an average annual rate of almost 3%, albeit with significant regional differences. Growth will be driven by healthy demand in Africa, mainland China, India, Indonesia, the Middle East, and South Korea. These markets consumed nearly 60% of total world LAB demand in 2020. Since about 2015, consumption of LAB in India has exceeded LAB consumption in mainland China. India still uses a lot of powder detergents, whereas liquid detergents are growing in mainland China. If crude oil prices (and consequently prices for LAB’s raw materials n-paraffins and benzene) increase significantly during 2020–25, consumption could grow at a slightly lower rate. Additionally, if there is a big switch to competing oleochemical-based surfactants (particularly in the developing regions and primarily as a result of possible lower fatty alcohol prices in the future compared with LAB), this will also negatively affect LAB consumption, as countries like mainland China will switch detergent formulations. Given the global pandemic, however, higher demand for cleaning products will likely stick around, especially with consumer’s heighted cleaning standards in a postpandemic world, benefitting the market for LAB.

In mature markets, like North America, Western Europe, and Japan, consumption will be decreasing, flat, or modestly increasing at best. This is a result of efforts of the detergent manufacturers to introduce new products that contain less surfactant per washload. In recent years, liquid laundry detergents (including unit dose packs, especially in the United States) have become more popular with consumers, and therefore, consumption of powder laundry detergent (traditionally containing significant amounts of LAS) has been decreasing. More recently, after a surge in laundry (washload basis and some stockpiling) in 2020 brought about by the COVID-19 pandemic, the North American laundry market is expected to decrease and then stabilize (washload basis) over the 2020–25 period. However, total demand is expected to remain above prepandemic levels.

Regions with still-developing markets that have significantly lower consumption of detergents per capita (although this is changing), like Asia, Central and South America, the Middle East, and Africa, are expected to register an increase in demand between 2% and 4% annually

Worldwide production and consumption of BAB has steadily decreased over the years. Increased availability of LAB, its competitive pricing, and the concerns associated with the low biodegradability of BAS have led to the steady decline of BAB demand. This trend is expected to continue over the forecast period, and both production and consumption of this product will decline, although at a slower rate.

For more detailed information, see the table of contents, shown below.

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Table of Contents

Section Page Number

Executive summary 6
Summary 7
Manufacturing processes 12
Linear alkylbenzene 12
Monochloroparaffin process 12
Linear internal olefins process 13
Linear alpha-olefins process 14
Branched alkylbenzene 14
Environmental issues 15
Supply and demand by region 16
North America 16
Producing companies 16
Linear alkylbenzene 16
Branched alkylbenzene 17
Salient statistics 17
Linear alkylbenzene 17
Branched alkylbenzene 18
Consumption 18
Linear alkylbenzene 18
Branched alkylbenzene 19
Price 20
Trade 21
Imports 21
Linear alkylbenzene 21
Branched alkylbenzene 21
Exports 22
Linear alkylbenzene 22
Branched alkylbenzene 23
Mexico 23
Central and South America 24
Central America and the Caribbean 24
South America 24
Western Europe 26
Producing companies 27
Salient statistics 28
Consumption 29
Price 31
Trade 31
Imports 31
Exports 32
Central and Eastern Europe 33
Producing companies 33
Salient statistics 34
Trade 35
Imports 35
Exports 36
Middle East 36
Producing companies 36
Salient statistics 38
Trade 39
Imports 39
Exports 40
Africa 41
Producing companies 41
Salient statistics 42
Trade 43
Imports 43
Exports 44
Indian Subcontinent 44
Producing companies 45
Salient statistics 45
Consumption 47
Price 47
Trade 47
Mainland China 48
Producing companies 48
Salient statistics 50
Consumption 50
Price 52
Trade 53
Northeast Asia 53
Producing companies 53
Japan 54
South Korea 54
Taiwan 55
Salient statistics 55
Japan 55
South Korea 56
Taiwan 57
Consumption 58
Japan 58
Linear alkylbenzene 58
Branched alkylbenzene 58
South Korea 58
Taiwan 59
Price 59
Trade 59
Imports 59
Exports 60
Southeast Asia 61
Producing companies 61
Salient statistics 62
Indonesia 62
Thailand 63
Consumption 63
Indonesia 64
Thailand 64
Vietnam 64
Price 64
Trade 65
Import 65
Export 65
Additional resources 66
Revisions 67
Data Workbook 68
Notice 69

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