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Phosphoric Acid

Chemical Economics Handbook

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Published August 2021

Phosphoric acid (H3PO4) is the leading inorganic acid produced and consumed in terms of production value and it is the second largest in terms of volume—after sulfuric acid. By far its greatest use is in the manufacture of phosphate chemicals consumed primarily as carriers of phosphorus values in fertilizers. Use in the production of animal feeds is of secondary importance. Phosphoric acid is also used in the manufacture of phosphate chemicals for use in water treatment and detergent builders, dentifrices, fire control chemicals, and a host of smaller markets. Consumption of phosphoric acid for its acid properties is relatively small (e.g., treatment of metal surfaces, beverage acidulation). Phosphoric acid is the leading intermediate product or processing step between phosphate rock and the end markets for phosphorus in phosphate form.

The supply/demand balance for phosphoric acid is supply driven. If all the announced projects materialize, operating rates will improve. Emerging regions are heavily investing in downstream phosphate fertilizer production units. As a result, it is expected that older phosphoric acid production units in regions without indigenous phosphate rock reserves will come under additional pressure and will eventually be forced to close.

The following pie chart shows world consumption of phosphoric acid:

The primary market for phosphoric acid is the production of the phosphate fertilizer products—ammonium phosphates and triple superphosphates. Fertilizer production accounts for an estimated 80% of the global market for phosphoric acid and animal feed for about 6%. The remainder is consumed in a variety of industrial applications.

Since 2010, there have been several consolidations and capacity reductions in the United States. In Latin America, the first half of 2018 saw a reduction in demand for phosphate fertilizers because of lower food prices. In the second half, demand is expected to rise following increases in soybean prices.

Fueled by the rapid growth in the Chinese economy and the growing need for phosphate fertilizers, China has become the world’s largest producer and consumer of phosphoric acid. From 2008 to 2018, phosphoric acid capacity in China grew at an average annual rate of 3.1%. Phosphoric acid production and consumption grew at an average annual rate of 4.5% and 4.6%, respectively, during the same period. It is projected that phosphoric acid production and consumption in China will experience slower yet moderate growth between 2018 and 2023.

While phosphoric acid markets in both Western and Central Europe are fairly mature, capacity has been significantly expanded in Eastern Europe during 2013–18. With phosphate reserves being exploited in Kazakhstan and Turkmenistan, new phosphoric acid plants were built in these two countries. A new plant is expected to come onstream by 2020 in Dorogobuzh, Russia.

In the Middle East and Africa, Office Cherifien des Phosphates (OCP) Group and Ma’aden Phosphate Company (MPC) are both shaping and shaking the global phosphoric acid industry. Both companies are backward integrated into indigenous phosphate rock deposits and both are heavily investing in developing and expanding downstream facilities. Through its majority owned subsidiary Waad Al Shamaal Phosphate Industrial Complex, Ma’aden expanded its phosphoric acid production capacity in Saudi Arabia in 2017, while OCP expanded its production capacity in Morocco during 2013–18, with further expansions planned through 2023. Additional large-scale capacity additions through the forecast period have been announced in Algeria, Egypt, and Uganda.

The phosphoric acid market in India is the largest in Other Asia. India is the leading importer of phosphoric acid in 2018, accounting for over half of global trade.

The global supply/demand balance is supply driven. Overall and on a global level, the phosphoric acid market is expected to grow annually by almost 4% per year.

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Table of Contents

Section Page Number

Executive summary 7
Summary 8
Americas 9
Europe 9
Middle East and Africa 10
Mainland China 10
Other Asia 10
Introduction 11
Manufacturing processes 14
General 14
Manufacturing technology 14
Sulfuric acid route 14
Hydrochloric acid route 16
Nitric acid route 17
Raw materials 17
Phosphate rock 17
Sulfuric acid 18
Other materials18
By-products 18
Gypsum 18
Fluorine 19
Uranium 19
Concentration 19
Clarification 20
Defluorination 20
Refining (purification) 20
Properties 21
Regulations 23
Fertilizers 23
Detergents 23
Food 23
Feed 24
Other 24
Environmental issues 25
Supply and demand by region 27
World 27
Producing companies 28
Capacity and production 28
Consumption 31
Price 32
Trade 34
United States 35
Producing companies 35
Production capacity 37
Salient statistics 38
Production 39
Consumption 39
Fertilizer use 40
Animal feeds 41
Industrial uses 41
Price 42
Trade 43
Canada 44
Producing companies 44
Salient statistics 45
Consumption 46
Price 47
Mexico 48
Producing companies 48
Salient statistics 48
Consumption 49
Central and South America 50
Producing companies 50
Production capacity 53
Salient statistics 53
Production 54
Consumption 54
Trade 55
Western Europe 56
Producing companies 56
Production capacity 58
Salient statistics 59
Production 60
Consumption 62
Price 64
Trade 66
Central Europe 67
Producing companies 67
Production capacity 69
Salient statistics 70
Production 71
Consumption 72
Price 74
Trade 74
CIS and Baltic States 75
Producing companies 75
Production capacity 78
Salient statistics 79
Production 80
Consumption 81
Price 83
Trade 83
Middle East 84
Producing companies 84
Production capacity 86
Salient statistics 87
Production 88
Consumption 89
Price 91
Trade 91
Africa 93
Producing companies 93
Production capacity 96
Salient statistics 97
Production 98
Consumption 99
Price 101
Trade 101
Indian Subcontinent 103
Producing companies 103
Production capacity 105
Salient statistics 105
Production 106
Consumption 107
Price 109
Trade 111
Mainland China 112
Producing companies 112
Salient statistics 119
Production 120
Consumption 121
Fertilizer 122
DAP 122
MAP 122
TSP 123
Direct/other 123
Animal feeds 123
DCP 123
MCP 123
TCP 123
Industrial and other 124
Direct PA use 124
STPP 124
Other sodium phosphates 125
Calcium phosphates 125
Potassium phosphate 125
Other 125
Price 125
Trade 126
Japan 127
Producing companies 127
Production capacity 128
Salient statistics 129
Consumption 130
Price 131
Trade 131
Other Northeast Asia 132
Producing companies 132
Production capacity 133
Salient statistics 133
Consumption 134
Trade 135
Southeast Asia and Oceania 136
Producing companies 136
Production capacity 138
Salient statistics 139
Production 140
Consumption 140
Price 142
Trade 142
Additional resources 144
Revisions 146
Data Workbook 147
Notice 148

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